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Author Topic: Boiler bluing  (Read 1334 times)

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Boiler bluing
« on: June 06, 2021, 10:41:57 am »
Hi all,

I did some boiler restorations, including the bluing of the boiler.
I am using a Brazilian version of "Super blue" for ferrous metals which results mainly in a bluish grey color.
Sometimes it result in a brownish color,with the same chemical composition and immersion time, my best guess is that the composition of the brass has a influence on the color, but it could also be another factor which I am not aware of.

I always roughen the boiler with a grit 1000 sandpaper and water, this gives a more  consisting result.

I have never used chemicals for Brass, it look that they give a black color to the brass and the chemicals are definitely not for free.

After bluing and drying I wash off the remaining oxides and rub some light oil on it.

I hope somebody wants to share his experience/ideas in this post.


Regards,

Maurice



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Re: Boiler bluing
« Reply #1 on: June 06, 2021, 11:25:51 am »
Hello Maurice,

I have already written something on the subject in my thread "Another Doll & Co." at your suggestion. You are right, a separate post should be dedicated to the subject.

I have said in my above post that I use "Nerofor" from Ballistol for burnishing brass.

When I use "Nerofor" on brass, I get the following reaction: the coloration goes to brownish, but with a blue shimmer. The intensity of the coloration depends on the exposure time of the chemical to the material. After pretreating the material to be blued with citric acid to remove fingerprints and any oily residue, I coat the object with Nerofor until an even brown-black layer is formed. Then I leave the chemical on for varying lengths of time, depending on the degree of tinting I want to achieve. Then the object is washed off with clear water.

I have no idea what the blue tinting of the old steam engines looked like in the original. After all, that was 100 years ago. Meanwhile, after careful cleaning, all of my bronzed boilers have a brownish base tone with a blue sheen. I always try to preserve the original bluing. Damaged areas can be painted over perfectly with Nerofor, as described above. In any case, I have had only good experiences with the product. However, I have not tried any other agent.

I am not a chemist or metallurgist to be able to explain exactly how bronzing agents work. However, I suspect that the available agents do not differ much in their composition and mode of action.

However, looking at the boiler you showed, I think I can see that
the "blue stain effect" is somewhat stronger with Super Blue than with Nerofor. However, that may also be due to the time of exposure in each case. I would be interested in trying Super Blue.

Examples of my use of Nerofor can be found in this forum in the following thread:


https://www.officeofsteamforum.com/collections-pictures/doll-3441-in-new-splendor/
Cheers
Jürgen
Dealing with steam is one way of having fun in life.

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Re: Boiler bluing
« Reply #2 on: June 06, 2021, 11:41:06 am »
Hi Jurgen,

Thanks for your valuable input, from what I understand you paint the boiler directly with chemicals ?
I have tried that once, but it showed many stains, the result was not uniform, that why I use a solution with water.
I have never tried to pre-wash them with citric acid, I will definitely try that.


Thanks,


Maurice.

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Re: Boiler bluing
« Reply #3 on: June 06, 2021, 12:15:07 pm »
Hello Maurice,

There is a good reason why I paint my boilers with Nerofor. Nerofor is not cheap. 1 liter of the chemical costs about € 140.00. So you can imagine that I prefer to paint the boilers. This is a tedious business, but as you can see from my examples, with quite a respectable result.
Cheers
Jürgen
Dealing with steam is one way of having fun in life.

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Re: Boiler bluing
« Reply #4 on: June 06, 2021, 12:29:31 pm »
Hi Jurgen,

I use some stuff called True Blue, it comes in a 100ml bottle for about 17 euros.
I mix this 1:20 so I get 2 liters of buing chemicals.
This mixture will deteriorate whem exposed to sunlight, so keep it in a box and it will stay good for a very long time.
There will always be some contamination from the boiler or whatever you are bluing and eventually the chemicals will weaken.
I guess that "super blue" will work the same.


Maurice.


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Re: Boiler bluing
« Reply #5 on: June 06, 2021, 01:43:29 pm »
It may or may not be of interest but i have a book here that has blueing and other colours recipes the book is from 1977 and has formulas and processes for just about anything you can think off measurements used are ounces and grains and quarts and some of the chemicals will require translating to common english 

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Re: Boiler bluing
« Reply #6 on: June 06, 2021, 02:35:25 pm »
What is title of the book ?
If it can be shared in the forum, then YES please.


Maurice

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Re: Boiler bluing
« Reply #7 on: June 06, 2021, 03:13:10 pm »
Hello Maurice,

I have another question about "True Blue". Is this bruning agent suitable for non-ferrous metals? There are many bruning agents offered, but very few are suitable for non-ferrous metals. It is important to pay attention to this.
Cheers
Jürgen
Dealing with steam is one way of having fun in life.

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Re: Boiler bluing
« Reply #8 on: June 06, 2021, 07:10:56 pm »
Hello Jurgen,

True Blue is a product for carbon steel, especially made for gun bluing.
They also have a product for brass, I checked out a video and the color is dark brown/black, I have never tried it for that reason.

Maurice.

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Re: Boiler bluing
« Reply #9 on: June 07, 2021, 11:58:32 am »
Hello Maurice,

I am interested in the Brunnier agent that is suitable for brass. I am rather cautious about the agents for steel products. Finally, the treatment with all Brunnier agents triggers an oxidation process on the metals.  This oxidation prevents or at least delays a further oxidation process (in steel or iron, for example, rust).  A protective film is applied to the material.

I spoke on the phone a few years ago with the employee of a company that sells the agent "Gun Blue". The agent is used in the bruising of guns, that is, for a steel product. I wanted to know if the agent is also suitable for non-ferrous metals. He answered in the negative. You can understand that this made me a bit cautious. Perhaps the agent attacks non-ferrous metals too strongly for steel products.

I would appreciate it if there is a member in the forum who can make concrete statements on this.

I have another small tip. My wife put me on it years ago. She regularly cleans steel and brass fittings in the kitchen and bathroom with a paste called "lemon balm". Is also suitable for silver. I clean my brass boilers, which, when I get an old steam engine, are often very dirty with gummy oil or other substances usually in a citric acid bath (8 g citric acid to 1 liter of heated water). The citric acid dissolves quite incidentally any lime deposited in the boiler excellent. Any impurities still on the outside of the kettle after the bath are polished off with "lemon balm". Always works. Unfortunately, an existing bruenning is also removed together with the dirt.

Lemon balsam has the property that when a bright brass kettle is polished with it, a protective film is put on the brass at the same time. If a kettle is to be bruised after treatment with the agent, it must first be rubbed with citric acid or vinegar. Otherwise, the bruising agent will have no effect.

Under the attached link you can purchase "lemon balm" from Jemako.
Jemako is a Dutch company that, as far as I know, also sells outside Europe. The link is from German ebay.


https://www.ebay.de/itm/153901944282?chn=ps&norover=1&mkevt=1&mkrid=7071533165376683&mkcid=2&itemid=153901944282&targetid=4582627049753642&device=c&mktype=&googleloc=&poi=&campaignid=376712746&mkgroupid=1264439088661572&rlsatarget=pla-4582627049753642&abcId=9300540&merchantid=87778&msclkid=3b468b5a3f6b1dd7a351ebe47c95e0d8

Stay healthy
Cheers
Jürgen
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Re: Boiler bluing
« Reply #10 on: June 07, 2021, 12:51:38 pm »
Hi Jurgen,

Thanks for the tips, I am actually dutch and will check this Jemako stuff out, maybe can get it cheaper.

Even though True bleu is made for carbon steel (like Super blue) is works just fine, which makes wonder what the actual differences are and why it would not be suitable for Brass.
I stumbled upon a post from Danny, explaining how he does the bluing, aslo using balistol and other products:

https://www.stoomwereld.be/brass-steel-blue-patination/


I guess I just need to go buy the stuff and see for myself next restoration.

I wonder what recipes Josef,Jean,Ernst,Georges and Ignaz were using, maybe these are lost secrets.



Regards,

Maurice.

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Re: Boiler bluing
« Reply #11 on: June 07, 2021, 01:00:34 pm »
Very interesting thread. I have so far only used the blackening solution from Regner on brass, which turns it into a deep brownish black.

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Re: Boiler bluing
« Reply #12 on: June 07, 2021, 01:05:50 pm »
Hi KNO3,

Thanks for your comment, can you share some pictures ?
Can tou tell us more about the blackening process you are using ?


Regards,

Maurice

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Re: Boiler bluing
« Reply #13 on: June 07, 2021, 01:12:08 pm »
Of course. Here are some pictures of cylinders of an engine I have blackened with the Regner solution. Look at the last few pictures, with the cylinders before and after:
https://www.flickr.com/photos/28865130@N04/albums/72157622660772239

The process is easy, just place the cleaned parts into the solution (darkness varies with exposure time), then wash. However, a part of the dark surface oxide will go away with washing or handling the part, this is normal.

This is the chemical I have used: 
https://www.regner-dampftechnik.com/product-page/messingf%C3%A4rber-kaltbr%C3%BCnierer

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Re: Boiler bluing
« Reply #14 on: June 07, 2021, 01:34:52 pm »
Hi KNO3,

Thanks for you input, it has a deep black color, did you manage to get different colors with this solution ?


Regards,

Maurice